Overview
Introduction: This chapter explains how air and water — essential natural resources — become contaminated by harmful substances called pollutants. It introduces common air pollutants (smoke, dust, carbon monoxide, sulfur and nitrogen oxides, volatile organic compounds, particulate matter, greenhouse gases, CFCs) and common water pollutants (domestic sewage, industrial effluents, agricultural runoff, oil spills, pathogenic microbes and heavy metals). It links human activities (vehicles, industries, burning biomass, use of fertilizers, improper waste disposal) to pollution and describes immediate and long-term impacts on health, ecosystems and climate. Importance: Understanding air and water pollution helps students recognise risks to health (respiratory and waterborne diseases), biodiversity (fish kills, eutrophication), and global problems (acid rain, global warming, ozone depletion). The chapter emphasises the need for sustainable habits, pollution-control technologies and community action to protect public health and the environment. Key themes: identification of pollutants and their sources; effects of pollution on humans, animals and plants; processes such as eutrophication,…
Learning Objectives
- Define air pollution and name major natural and man-made sources.
- Explain how particulate matter, sulfur dioxide, nitrogen oxides, carbon monoxide and hydrocarbons affect air quality and human health.
- Describe the greenhouse effect and its connection to air pollution and global warming.
- Differentiate between primary and secondary air pollutants with suitable examples.
- Identify causes and effects of acid rain on soil, water bodies and buildings.
- Explain the formation of smog (photochemical and industrial) and state methods to control it.
- Define water pollution and list common pollutants and their point and non-point sources.
- Describe the effects of water pollution on aquatic life, human health and ecosystem services.
Topics in this chapter
15 topics · tap a topic title to jump straight to it.
Introduction to Pollution
Introduction to Pollution
Key Point: Concentration (mass/volume) = mass of pollutant / volume of medium. (e.g., mg/L for water; mg/m³ for air)
Pollution is the introduction of harmful substances or forms of energy (like heat, noise, or radiation) into the environment so that they cause undesirable effects to living organisms and the natural balance of ecosystems. Pollution may be visible (smoke, oil slicks) or invisible (gases, dissolved chemicals, microorganisms).
Main types relevant to Class 8:
- Air pollution: presence of harmful gases, dust, smoke and fumes in the atmosphere (examples: CO, CO2, SO2, NOx, suspended particulate matter, ground-level ozone).
- Water pollution: contamination of water bodies by chemicals, sewage, microbes, plastics, oil or excess nutrients (nitrates and phosphates) leading to reduced water quality.
Sources of pollution (brief):
- Natural: volcanic eruptions, forest fires, dust storms, decaying organic matter.
- Human-made (major): vehicle emissions, industrial effluents, coal and biomass burning, landfill leachate, sewage discharge, agricultural runoff (fertilisers and pesticides), oil spills and single-use plastics.
Primary and secondary pollutants:
- Primary pollutants are emitted directly (e.g., CO from vehicles, SO2 from factories, suspended dust).
- Secondary pollutants form in the air by chemical reactions (e.g., ground-level ozone, smog formed from NOx and volatile organic compounds under sunlight).
Effects of pollution:
- Health: respiratory diseases (asthma, bronchitis), heart problems, neurological damage (lead), water-borne diseases (cholera, dysentery).
- Environment: acid rain (from SO2 and NOx), eutrophication of lakes and rivers (from excess nitrates/phosphates), loss of aquatic life, reduced soil fertility, biodiversity loss.
- Climate: greenhouse gases (CO2, methane) trap heat and cause global warming and climate change.
Simple concepts to know:
- Concentration tells how much pollutant is present per unit volume or mass of the medium (for example mg/L in water or mg/m3 in air).
- ppm (parts per million) is a commonly used small-concentration unit: for dilute aqueous solutions 1 ppm ≈ 1 mg/L.
- Dilution: reducing concentration by adding more clean medium (C1V1 = C2V2 for simple dilution problems).
Prevention and control (basic measures):
- Reduce: use public transport, energy-efficient appliances, minimise single-use plastics.
- Reuse and recycle: treat and recycle industrial and household waste.
- Treatment: sewage treatment plants, effluent treatment for industries, air filtration and scrubbers.
- Regulation & awareness: emission standards, proper disposal rules, community education, planting trees.
Key takeaway: Pollution is avoidable and manageable by changing human behaviour, applying simple scientific ideas (monitoring concentrations, treating wastes) and following laws and good practices. Understanding sources, measuring concentrations, and using control methods helps protect health and ecosystems.
- Vehicular exhaust producing carbon monoxide and particulate matter in cities.
- Factory chimneys releasing sulfur dioxide that can cause acid rain.
- Untreated sewage discharged into rivers causing waterborne diseases and oxygen depletion.
- Agricultural runoff containing fertilisers causing algal blooms and eutrophication in lakes.
- Burning crop residues or garbage producing smoke and increasing indoor/outdoor air pollution.
- Oil spills in oceans harming marine life and coating birds' feathers.
- \[Concentration (mass/volume) = mass of pollutant / volume of medium. (e.g.\]\[mg/L for water\]\[mg/m³ for air)\]
- \[ppm (parts per million) ≈ (mass of pollutant in mg) / (volume of water in L)\]\[For dilute aqueous solutions 1 ppm ≈ 1 mg/L.\]
- \[Dilution relation: C1 × V1 = C2 × V2 (useful to calculate how concentration changes when mixing or diluting).\]
- \[Approximate conversion (gas): mg/m³ = ppm × (molecular weight) / 24.45 — valid near 25°C and 1 atm (24.45 is molar volume in L/mol at 25°C).\]
Air — Composition and Importance
Air — Composition and Importance
Key Point: Ideal gas law (air behaves approximately as an ideal gas): PV = nRT
What is air?
Air is a mixture of many gases, tiny liquid droplets and solid particles. When we talk about the composition of air we generally mean dry air (without water vapour). Air surrounds the Earth and is essential for life and many physical and chemical processes.
Composition of dry air (approximate by volume)
- Nitrogen (N2): 78.08% — most abundant, largely inert, important for the nitrogen cycle and fertilizers.
- Oxygen (O2): 20.95% — essential for respiration and combustion.
- Argon (Ar): 0.93% — an inert noble gas.
- Carbon dioxide (CO2): ≈0.04% (about 400–420 ppm) — essential for photosynthesis; a greenhouse gas.
- Neon, helium, methane, krypton, hydrogen, xenon and other trace gases: together <0.01%.
- Water vapour (H2O): variable, typically 0–4% (depends on temperature and humidity).
- Ozone (O3): present in trace amounts; concentrated in the stratosphere (ozone layer) where it protects life from UV radiation.
Why specify dry air?
Because water vapour percentage changes with weather and temperature. The values above are for dry air (no water vapour).
Importance of air
- Respiration: Oxygen in air is used by animals and humans to produce energy in cells.
- Photosynthesis: Plants use CO2 and produce O2 — the balance of gases sustains life. (See photosynthesis equation in formulas.)
- Combustion and industry: Oxygen supports burning; many industrial processes require specific gases from air.
- Climate and weather: Water vapour and greenhouse gases (CO2, CH4) control temperature and weather patterns.
- Protection from UV: The ozone layer in the stratosphere absorbs harmful ultraviolet rays from the Sun.
- Dilution and transport of pollutants: The atmosphere carries and disperses gases and particles (but excessive pollutants cause smog and health problems).
- Sound propagation and flight: Air is the medium for sound and is necessary for aerodynamic lift (flight).
Effects of changes in composition
Small changes in trace gases can have large effects: rising CO2 increases the greenhouse effect and global temperatures; increased particulate matter and NOx/SOx from vehicles and industry cause smog, respiratory diseases and acid rain; ozone depletion increases UV exposure.
Simple numeric illustration — partial pressure
Air is a mixture: each gas contributes to the total pressure. At sea level (total pressure ≈ 101.3 kPa): partial pressure of oxygen ≈ 0.2095 × 101.3 ≈ 21.2 kPa. For CO2 at 400 ppm (0.0004 fraction): partial pressure ≈ 0.0004 × 101.3 ≈ 0.0405 kPa.
Takeaway
Air composition is mostly nitrogen and oxygen with small amounts of other gases. These proportions and the presence of variable water vapour and trace gases determine life-supporting processes, climate, weather, and human health.
- Breathing: Humans inhale air with ~21% oxygen; cells use O2 to release energy from food.
- Photosynthesis: Plants take in CO2 from the air and release oxygen — this keeps atmospheric O2 and CO2 balanced locally.
- Combustion in car engines: Oxygen from air reacts with fuel to produce CO2 and H2O; incomplete combustion can produce CO and particulates (pollution).
- Ozone layer protection: Ozone in the stratosphere absorbs harmful UV radiation; chlorofluorocarbons (CFCs) caused ozone depletion, increasing UV-related skin problems.
- Urban smog: In cities, NOx and volatile organic compounds (VOCs) + sunlight form photochemical smog, reducing air quality and visibility.
- Greenhouse effect: Increased CO2 (from fossil fuel burning) traps more heat and contributes to global warming — illustrated by rising atmospheric CO2 measurements over time.
- \[Ideal gas law (air behaves approximately as an ideal gas): PV = nRT\]
- \[Partial pressure of component i: Pi = Xi × Ptotal (Xi = mole fraction of gas i)\]\[Example: PO2 ≈ 0.2095 × 101.3 kPa ≈ 21.2 kPa at sea level.\]
- \[Convert ppm to fraction: fraction = ppm / 1,000,000\]\[Example: 400 ppm CO2 = 0.000400 = 0.0400%.\]
- \[Photosynthesis (simplified): 6 CO2 + 6 H2O → C6H12O6 + 6 O2\]
- \[Complete combustion (methane example): CH4 + 2 O2 → CO2 + 2 H2O\]
- \[Acid rain formation (simple steps): SO2 + H2O → H2SO3 (sulfurous acid)\]\[SO2 oxidised to SO3 then SO3 + H2O → H2SO4 (sulfuric acid)\]
Air Pollution — Definition and Sources
Air Pollution — Definition and Sources
Key Point: Percent by volume of a gas: (volume of pollutant gas / total volume of air) × 100 %
Definition
Air pollution is the presence of harmful substances — gases, particles or biological molecules — in the atmosphere in concentrations that can harm human health, animals, vegetation, or materials and disturb the natural balance of the environment.
Types of Air Pollutants
Primary pollutants are emitted directly from a source (for example, carbon monoxide from vehicle exhaust). Secondary pollutants form in the air by chemical reactions between primary pollutants (for example, ground-level ozone formed when nitrogen oxides and volatile organic compounds react in sunlight).
Sources of Air Pollution
Sources are usually grouped as natural or human-made (anthropogenic):
- Natural sources: dust storms, volcanic eruptions (ash and sulfur compounds), forest fires (smoke and particles), pollen and spores, sea spray (salt particles).
- Human-made (anthropogenic) sources: industrial emissions (factories, refineries, power plants releasing SO2, NOx, particulates), vehicles (cars, buses, trucks emitting CO, NOx, hydrocarbons and particles), burning of fossil fuels (coal, oil, petrol and diesel), biomass burning and open waste burning (smoke, particulates, toxic gases), household combustion (wood, coal, kerosene used for cooking/heating producing indoor air pollution), construction and mining (dust and particulates), use of solvents and aerosols (volatile organic compounds), agricultural activities (ammonia from fertilizers, burning crop residue).
Effects (brief)
Air pollution can cause respiratory and heart diseases, reduce crop yields, corrode buildings, reduce visibility (smog) and contribute to climate change (greenhouse gases like CO2).
- Severe winter smog episodes in Delhi caused by vehicle emissions, crop-residue burning in neighbouring states, dust and low wind speed (high PM2.5 and PM10).
- The London Great Smog of 1952: coal-burning domestic and industrial emissions caused thousands of deaths and led to clean-air laws.
- Forest fires in Australia (2019–2020) produced large plumes of smoke, raising PM concentrations over cities and causing respiratory problems.
- Indoor air pollution in rural homes from cooking with biomass (wood, dung) causing chronic respiratory illnesses.
- Factories and coal-fired power plants emitting sulfur dioxide (SO2) and nitrogen oxides (NOx) that can produce acid rain and particulate pollution.
- \[Percent by volume of a gas: (volume of pollutant gas / total volume of air) × 100 %\]
- \[Parts per million (ppm): ppm = (volume of pollutant / total volume) × 10^6\]\[useful for very dilute gases.\]
- \[Conversion approximate (at 25°C and 1 atm): mg/m3 = ppm × (molecular weight / 24.45)\]\[Example: for SO2 (MW ≈ 64 g/mol), 1 ppm ≈ 64/24.45 ≈ 2.62 mg/m3.\]
- \[Representative chemical equations for common pollutants and reactions: - Complete combustion of carbon: C + O2 → CO2 - Incomplete combustion (carbon monoxide): 2C + O2 → 2CO - Sulfur in fuel to sulfur dioxide: S + O2 → SO2 - Formation of nitrogen oxides at high temperature: N2 + O2 → 2NO (then 2NO + O2 → 2NO2) - Ozone (ground-level) formation simplified: NO2 + sunlight (hv) → NO + O\]\[O + O2 → O3 (with VOCs enhancing ozone production)\]
Major Air Pollutants
Major Air Pollutants
Key Point: Complete combustion of carbon: C + O2 → CO2
What are major air pollutants?
Major air pollutants are substances in the air that have harmful effects on human health, animals, plants, materials and climate. They come from natural and human (anthropogenic) sources.
- Carbon monoxide (CO): A colourless, odourless gas formed by incomplete combustion of carbon-containing fuels (vehicles, stoves, forest fires). It reduces oxygen transport in the blood and can be fatal in high concentrations.
- Sulphur dioxide (SO2): Produced when fuels containing sulphur (coal, oil) are burned in power plants or industries. SO2 irritates eyes and respiratory tract and contributes to acid rain.
- Nitrogen oxides (NO, NO2 — collectively NOx): Formed at high temperatures in vehicle engines and thermal plants (N2 + O2 → 2NO). NOx causes respiratory problems and helps form photochemical smog and acid rain.
- Particulate matter (PM): Tiny solid or liquid particles (dust, soot, smoke). PM10 (diameter ≤10 μm) and PM2.5 (diameter ≤2.5 μm) penetrate lungs and blood, causing heart and lung diseases.
- Hydrocarbons / Volatile Organic Compounds (VOCs): Emitted from petrol, solvents, paints and vegetation. In sunlight they react with NOx to make ozone (O3) and smog.
- Ozone (tropospheric O3): A secondary pollutant formed when NO2 and VOCs react in sunlight (NO2 + hv → NO + O; O + O2 → O3). Ground-level ozone irritates lungs and damages crops.
- Lead (Pb) and other heavy metals: From old leaded petrol, battery recycling, metal industries. They are toxic, affecting nervous system and development in children.
Sources: Vehicles, power plants, industries, burning of biomass or waste, construction, dust storms, volcanic activity and household fuels.
Effects: Respiratory and cardiovascular illness, reduced visibility, crop damage, material corrosion, acid rain (damaging lakes/forests), and contribution to climate change (some pollutants).
Control measures (brief): Use cleaner fuels and technologies, fit catalytic converters, install filters and scrubbers in industries, prevent open burning, control dust at construction sites, shift to public transport and renewable energy, and enforce emission standards.
- Vehicle exhaust releasing CO and NO2 in busy city roads — causes breathing problems and smog in urban areas.
- Coal-fired power plant emitting SO2 and fly ash — contributes to acid rain and particulate pollution nearby.
- Stubble/crop burning and forest fires producing large amounts of smoke (PM2.5) that reduce visibility and increase hospital visits.
- Construction sites producing dust (PM10) — causes local increase in particulate pollution.
- Use of kerosene stoves or indoor burning without ventilation producing CO and particulates — indoor air pollution risk.
- Photochemical smog in sunny cities (e.g., Los Angeles) where VOCs + NOx + sunlight form ozone, irritating eyes and lungs.
- \[Complete combustion of carbon: C + O2 → CO2\]
- \[Incomplete combustion (produces carbon monoxide): 2C + O2 → 2CO\]
- \[Sulfur oxidation: S + O2 → SO2\]
- \[Nitrogen fixation at high temperature: N2 + O2 → 2NO\]\[2NO + O2 → 2NO2\]
- \[Ozone formation (photochemical): NO2 + hv → NO + O\]\[O + O2 → O3\]
- \[Acid rain formation (simplified): SO3 + H2O → H2SO4\]\[NO2 + OH → HNO3\]
Effects of Air Pollution
Effects of Air Pollution
Key Point: ppm (parts per million) = (volume of pollutant / total air volume) × 10^6
Air pollution occurs when harmful substances — gases, particles and biological molecules — are introduced into the atmosphere in concentrations that cause harm to living beings, materials and the environment. The effects of air pollution are wide-ranging and can be grouped into effects on human health, animals, plants and crops, materials/buildings, and the global environment.
- Effects on human health:
- Short-term: irritation of eyes, nose and throat, coughing, breathlessness, eye infections, headaches and allergic reactions.
- Long-term: chronic bronchitis, aggravated asthma, reduced lung function, cardiovascular diseases and increased risk of lung cancer. Children, the elderly and people with pre-existing illnesses are most vulnerable.
- Effects on animals:
- Respiratory problems, reduced reproduction and increased mortality in sensitive species. Birds and mammals living in polluted areas show decreased fitness and population declines in extreme cases.
- Effects on plants and crops:
- Air pollutants such as SO2, NO2 and ozone damage leaves, reduce photosynthesis and stunt growth. This lowers crop yields and can change forest composition. Visible symptoms include chlorosis (yellowing), necrosis (dead patches) and early leaf drop.
- Effects on materials and buildings:
- Acidic pollutants (SO2, NOx) and suspended particles corrode metals, erode stone and damage paint. Historical monuments, statues and buildings (e.g., marble) suffer surface erosion and discoloration.
- Regional and global environmental effects:
- Smog: Inversions and high pollutant levels cause photochemical smog (brownish smog with O3 and PAN) or classical smog (mixture of smoke and fog), reducing visibility and harming health.
- Acid rain: SO2 and NOx react to form sulfuric and nitric acids, which fall with rain and damage soils, freshwater ecosystems, plants and buildings.
- Greenhouse effect and climate change: Increased concentrations of CO2, CH4 and other greenhouse gases trap heat and lead to global warming, changing weather patterns and sea levels.
- Ozone layer depletion: Certain industrial chemicals (CFCs) destroy stratospheric ozone, increasing UV radiation at Earth’s surface and raising risks of skin cancer and ecosystem damage.
Overall, air pollution reduces quality of life, increases healthcare costs, lowers agricultural productivity and accelerates material degradation. Preventive actions (clean fuels, emission controls, green cover, regulations) reduce these effects.
- Great London Smog (1952): A severe smog event caused thousands of deaths due to coal smoke and weather inversion — an early example showing health risks of urban air pollution.
- Delhi winter smog: High levels of PM2.5 from vehicle emissions, crop stubble burning and cold inversion cause spikes in respiratory hospital admissions every winter.
- Acid rain in industrial regions of Europe and North America: SO2 and NOx emissions led to forest damage and acidified lakes, harming fish populations and forests.
- Yellowing and corrosion of marble monuments (e.g., Taj Mahal area concerns) due to SO2 and particulate deposition.
- Ozone hole over Antarctica: CFC emissions led to stratospheric ozone depletion, increasing UV radiation reaching Earth.
- \[ppm (parts per million) = (volume of pollutant / total air volume) × 10^6\]
- \[mg/m^3 (at 25°C, 1 atm) ≈ (ppm × molecular weight) / 24.45 — useful to convert gaseous pollutant concentrations between ppm and mass/volume units\]
- \[Simplified AQI sub-index conversion (used by many indices): I = ((I_high - I_low)/(C_high - C_low)) × (C - C_low) + I_low\]\[where C is measured concentration and I is the corresponding AQI value between I_low and I_high for the concentration range [C_low\]\[C_high].\]
- \[Acid rain formation (simplified chemical steps): SO2 + H2O → H2SO3 (sulfurous acid) and further oxidation: 2SO2 + O2 → 2SO3\]\[SO3 + H2O → H2SO4 (sulfuric acid)\]\[Also: 2NO2 + H2O → HNO2 + HNO3 (nitrous and nitric acid formation).\]
Control and Prevention of Air Pollution
Control and Prevention of Air Pollution
Key Point: Filter / scrubber efficiency (%) = ((C_in - C_out) / C_in) × 100, where C_in = pollutant concentration before control, C_out = concentration after control.
Control and Prevention of Air Pollution
Air pollution occurs when harmful substances (gases, smoke, particles) enter the atmosphere in concentrations that can harm human health, animals, plants or materials. Control and prevention of air pollution means reducing these emissions at the source, removing pollutants during transport, or reducing exposure at the receptor (people, buildings).
Major approaches
- Source control (most effective): Stop or reduce the emission of pollutants where they are produced. Examples: use cleaner fuels, change processes, and maintain vehicles and machines.
- End-of-pipe control / pollution control devices: Capture or transform pollutants before they reach the atmosphere. Examples: filters, electrostatic precipitators, scrubbers, catalytic converters.
- Regulatory and planning measures: Laws, standards and urban planning to limit emissions and exposure—vehicle emission standards, industrial permits, relocation of polluting industries, and zoning.
- Behavioral and community actions: Public transport, car-pooling, tree planting, avoiding open burning and promoting clean cooking solutions.
Practical control measures (with simple explanations)
- Cleaner fuels and technologies: Replace coal/wood with LPG, CNG, electricity or improved cookstoves. Cleaner fuel produces fewer smoke and harmful gases.
- Vehicle measures: Regular maintenance, proper tyre pressure, catalytic converters, phased introduction of cleaner fuel standards (e.g., Bharat Stage/Euro norms), promotion of public transport and non-motorized transport (walking, cycling).
- Industrial controls: Use of electrostatic precipitators (ESPs) and baghouse filters for particulate removal; wet or dry scrubbers for SO2 and acid gases; ensuring adequate stack height to dilute emissions and disperse pollutants safely; process changes to reduce raw pollutant generation.
- Agricultural practices: Avoid open field burning of crop residue. Use alternatives like happy seeder machines, straw incorporation, creation of biogas from residues, or use of residue as animal fodder or compost.
- Municipal measures: Proper waste management to stop open burning of garbage, dust control on roads by sweeping and sprinkling water, and control of construction dust with nets and water sprays.
- Indoor air improvement: Ventilation, chimneys for kitchens, use of clean cookstoves and fuels, exhaust fans and air purifiers where necessary.
- Afforestation and green belts: Planting of trees and creating green belts around industrial areas and roads to trap dust and absorb some gaseous pollutants.
Why multiple measures are needed
No single solution removes all pollutants. For example, filters remove particles but not gases; scrubbers can remove gases but need treatment of wastewater. Combining cleaner fuels, good technology, regulation and community action gives the best results.
Small actions that help
- Use public transport, cycle or walk when possible.
- Avoid burning leaves, plastics or trash at home.
- Get vehicles checked and ensure pollution control certificates (PUC where required).
- Use energy-efficient electrical appliances and reduce waste burning.
These measures protect health, reduce smog, improve visibility and lower acid deposition and damage to crops and buildings.
- Delhi's shift of many city buses to CNG reduced emissions of particulate matter and carbon monoxide from public transport.
- Thermal power plants use electrostatic precipitators (ESPs) to remove fly ash particles from flue gases before release through stacks.
- Farmers in Punjab use the 'Happy Seeder' machine to sow wheat directly into rice stubble instead of burning straw, reducing seasonal crop-burning smoke that worsens Delhi's air quality.
- Households replacing traditional wood stoves with LPG or improved cookstoves significantly reduce indoor smoke (respirable particulate matter) and improve health of women and children.
- Implementation of vehicle emission standards (Bharat Stage / Euro norms) reduces permitted limits for NOx, CO and hydrocarbons in vehicle exhausts.
- \[Filter / scrubber efficiency (%) = ((C_in - C_out) / C_in) × 100\]\[where C_in = pollutant concentration before control\]\[C_out = concentration after control.\]
- \[Convert concentration between ppm and µg/m³ (approx. at 25 °C and 1 atm): µg/m³ = ppm × (molecular weight) × 1000 / 24.45\]\[Rearranged: ppm = (µg/m³ × 24.45) / (molecular weight × 1000). (Use molecular weight of pollutant gas.)\]
- \[AQI sub-index linear interpolation (used in many AQI systems): I = I_low + (I_high - I_low) × (C - C_low) / (C_high - C_low)\]\[where C is pollutant concentration and I the index mapped between breakpoints (C_low\]\[C_high) and (I_low\]\[I_high).\]
- \[Dilution: C_after = (Q_source × C_source) / (Q_source + Q_air)\]\[where Q_source is pollutant-emitting air flow and Q_air is mixing ambient airflow (simple mass-balance dilution estimate).\]
Water — Importance and the Water Cycle (brief)
Water — Importance and the Water Cycle (brief)
Key Point: Mass from volume: mass (m) = density (ρ) × volume (V). Example: m = ρ × V. (For water, ρ ≈ 1 g/cm³ or 1000 kg/m³ at 4°C.)
Why water is important
Water is essential for all living organisms. It acts as a medium for biochemical reactions, helps regulate body temperature, transports nutrients and wastes, and is needed for growth, digestion and photosynthesis. Water also shapes Earth’s climate, supports agriculture and industry, and maintains ecosystems (rivers, lakes, wetlands).
Key physical properties (short)
Water is a universal solvent, has high specific heat, large latent heat of vaporization, cohesion and adhesion (surface tension), and exists in three states (solid, liquid, gas) at Earth temperatures. These properties make water vital for life and for transferring heat and energy in the environment.
The water cycle (brief steps)
- Evaporation — Liquid water from oceans, lakes and soil turns into water vapour when heated by the Sun.
- Transpiration — Plants release water vapour from leaves into the air (often combined with evaporation as evapotranspiration).
- Condensation — Water vapour cools and forms tiny droplets, creating clouds and fog.
- Precipitation — Droplets combine and fall as rain, snow, sleet or hail back to Earth.
- Infiltration and Percolation — Some rain soaks into the ground to recharge groundwater (aquifers).
- Runoff — Water that doesn’t infiltrate flows over land into rivers, lakes and oceans, completing the cycle.
Human impact and pollution (brief)
Human activities (industrial discharge, sewage, agricultural runoff, plastic waste) pollute water bodies, disrupting ecosystems and making water unsafe for drinking. Overuse and groundwater extraction lower water tables and reduce freshwater availability. Conserving water, preventing pollution and treating wastewater are essential.
Conservation tips (short)
Fix leaks, use water-efficient fixtures, practise rainwater harvesting, avoid dumping waste into drains, use drip irrigation in agriculture, and treat/ reuse wastewater where possible.
- After a hot day, puddles and wet soil dry up due to evaporation; the evaporated water later forms clouds (evaporation → condensation → precipitation).
- Plants release water vapour from their leaves (transpiration), which contributes to local humidity and cloud formation—important in forests and agriculture.
- A river fed by melting mountain snow and glacier runoff shows seasonal changes in water flow driven by the water cycle.
- Domestic water use: cooking, cleaning, bathing and flushing — shows why safe freshwater supply is critical for health.
- Agricultural irrigation uses the largest share of freshwater in many countries; inefficient irrigation can lead to water scarcity and runoff pollution.
- Industrial discharge of chemicals into a lake can contaminate drinking water sources and harm aquatic life, illustrating pollution’s effect on the water cycle.
- \[Mass from volume: mass (m) = density (ρ) × volume (V)\]\[Example: m = ρ × V. (For water, ρ ≈ 1 g/cm³ or 1000 kg/m³ at 4°C.)\]
- \[Heat required to change temperature: Q = m × c × ΔT\]\[where c (specific heat of water) ≈ 4.18 J/g°C (or 4180 J/kg°C).\]
- \[Heat for phase change (evaporation/condensation): Q = m × L\]\[where L (latent heat of vaporization for water) ≈ 2260 J/g (2.26×10^6 J/kg).\]
- \[Flow rate (useful for rivers): discharge Q = A × v\]\[where A = cross-sectional area and v = average velocity.\]
- \[Earth's water distribution (useful percentages): ≈ 71% of Earth's surface is water\]\[about 97% of that is saline ocean water and ~3% is freshwater (of which ~2.5% is frozen in glaciers and polar ice).\]
Water Pollution — Definition and Sources
Water Pollution — Definition and Sources
Key Point: ppm and mg/L: For dilute aqueous solutions 1 ppm ≈ 1 mg/L (parts per million ≈ milligrams per litre).
Definition: Water pollution is the contamination of water bodies (rivers, lakes, ponds, oceans, groundwater) by substances that make the water harmful for living organisms and unsuitable for its intended uses (drinking, bathing, irrigation, or supporting aquatic life).
What causes water pollution? Pollutants are introduced into water from many activities. They can be chemicals, biological agents (pathogens), heat, plastics and other solid wastes, or radioactive material. Pollutants reduce water quality and can kill fish, plants and microbes that maintain a healthy ecosystem.
Types of sources:
- Point sources: Specific, identifiable sources such as the outlet of a factory, sewage pipe, or drainage channel. These are easier to monitor and control.
- Non-point sources: Diffuse sources that are spread out and harder to trace—for example, agricultural runoff, urban stormwater, or atmospheric deposition.
Major sources explained:
- Domestic sewage: Wastewater from homes contains organic matter, detergents, toilet waste and pathogens. Untreated sewage raises biological oxygen demand and spreads diseases.
- Industrial effluents: Factories may release acids, heavy metals (lead, mercury, cadmium), dyes and toxic organic chemicals. These can poison aquatic life and accumulate in the food chain.
- Agricultural runoff: Fertilisers (nitrates and phosphates), pesticides and animal waste wash into water bodies. Excess nutrients cause eutrophication—excessive algal growth that depletes oxygen.
- Oil spills: From ships, pipelines or offshore drilling. Oil coats surfaces, harming birds and marine animals and damaging habitats.
- Plastic and solid waste: Plastics, polythene bags and other garbage block waterways, harm animals that ingest or get entangled, and slowly degrade into microplastics.
- Thermal pollution: Hot water discharged from power plants raises water temperature, reducing dissolved oxygen and stressing aquatic organisms.
- Radioactive and mining waste: Radioactive material and mineral wastes contaminate water with long-lasting and dangerous pollutants.
Effects of water pollution (brief): Spread of waterborne diseases (cholera, typhoid), reduction of dissolved oxygen causing fish kills, bioaccumulation of toxins in food chains (e.g., mercury), loss of biodiversity, unsafe drinking water and damage to livelihoods (fisheries, tourism).
Prevention (short): Treat sewage before discharge, regulate industrial effluents, use organic farming and controlled fertiliser use, proper disposal and recycling of plastics, clean-up of oil spills and public awareness to reduce pollution.
- Yamuna River near Delhi receives untreated sewage and industrial waste, causing low water quality and large algae growth.
- Minamata disease (Japan): mercury released from an industrial plant accumulated in fish and caused severe health effects in humans who ate the fish.
- 2010 Deepwater Horizon oil spill in the Gulf of Mexico coated marine life and shorelines, causing long-term damage to ecosystems.
- Algal blooms in lakes (e.g., parts of Lake Erie) caused by excess fertilizers; blooms reduce oxygen and kill fish.
- Plastic waste in oceans: turtles and seabirds ingest or get entangled in plastic bags and nets, often with fatal results.
- \[ppm and mg/L: For dilute aqueous solutions 1 ppm ≈ 1 mg/L (parts per million ≈ milligrams per litre).\]
- \[Biochemical Oxygen Demand (BOD) basic relation: BOD = DO_initial − DO_final (after incubation\]\[usually 5 days at 20°C for BOD5)\]\[Units: mg/L.\]
- \[Percent removal of a pollutant: % removal = ((C_initial − C_final) / C_initial) × 100\]\[where C are concentrations (mg/L).\]
- \[Simplified relation for oxygen depletion: Lower dissolved oxygen (DO) often correlates with higher organic pollution\]\[DO is measured in mg/L.\]
Major Water Pollutants and Their Nature
Major Water Pollutants and Their Nature
Key Point: BOD5 (mg/L) = DO_initial - DO_after_5_days (at 20°C). BOD is a measure of biodegradable organic matter that consumes oxygen.
What is a water pollutant? A water pollutant is any substance (solid, liquid or gas) present in water that makes it unsuitable for its intended use — drinking, bathing, irrigation or supporting aquatic life.
Classification by nature
- Physical pollutants: Suspended solids (silt, sand), microplastics and temperature changes (thermal pollution). They reduce water clarity, block sunlight and can smother aquatic habitats.
- Chemical pollutants: Dissolved salts, acids & alkalis, heavy metals (lead, mercury, cadmium), organic chemicals (phenols, dyes, oil), and nutrients (nitrates, phosphates). These can be toxic, change pH, or cause chemical reactions that harm life.
- Biological pollutants (pathogens): Bacteria (E. coli, Vibrio), viruses, protozoa and parasitic worms from untreated sewage that cause water-borne diseases.
- Radioactive pollutants: Radioisotopes from nuclear waste; cause long-term genetic damage and are persistent.
Classification by degradability and source
- Biodegradable: Organic matter (sewage, food wastes) that microbes can decompose. High loads increase Biological Oxygen Demand (BOD).
- Non-biodegradable / persistent: Heavy metals, many synthetic organic chemicals and plastics that do not break down easily and can bioaccumulate.
- Point sources: Identifiable sources like factory effluents, sewage outfalls and drains.
- Non-point sources: Diffuse sources like agricultural runoff delivering fertilisers and pesticides, urban stormwater.
How pollutants affect water and life
- Eutrophication: Excess nitrates and phosphates (from fertilisers and detergents) stimulate algal blooms. When algae die, decomposition consumes dissolved oxygen → fish kills and reduced biodiversity.
- Toxic effects: Heavy metals and industrial chemicals can poison aquatic organisms and accumulate up the food chain, affecting humans.
- Pathogen contamination: Causes cholera, dysentery, typhoid and other diseases when people use polluted water.
- Physical harm: Oil films reduce oxygen transfer, thermal pollution lowers dissolved oxygen, and plastics entangle or choke wildlife.
Control and prevention (brief)
- Sewage treatment (primary/secondary) to reduce BOD and pathogens.
- Effluent treatment plants for industries and regulation of hazardous discharges.
- Reduce fertiliser and pesticide runoff: sustainable agriculture, buffer strips.
- Oil-spill response, banning/reducing single-use plastics, and proper waste disposal.
Summary: Major water pollutants are physical (silt, plastics, heat), chemical (nutrients, heavy metals, oils, acids), biological (pathogens) and radioactive substances. Their nature—soluble vs suspended, biodegradable vs persistent, toxic vs non-toxic—determines treatment methods and environmental impact.
- Household sewage rich in organic matter and pathogens discharged into rivers causing high BOD and water-borne diseases.
- Agricultural runoff carrying nitrates and phosphates leading to algal blooms and eutrophication in lakes.
- Textile mill effluents containing dyes and chemicals contaminating local streams and harming aquatic life.
- Heavy-metal contamination (e.g., mercury) from mining causing bioaccumulation and illnesses such as Minamata disease.
- Oil spills (Exxon Valdez, Deepwater Horizon) coating marine life and shorelines, reducing oxygen transfer and causing long-term damage.
- Plastic waste (bags, bottles) and microplastics that persist in water, are ingested by animals and enter the food chain.
- \[BOD5 (mg/L) = DO_initial - DO_after_5_days (at 20°C)\]\[BOD is a measure of biodegradable organic matter that consumes oxygen.\]
- \[COD (mg/L) ≈ (Volume_of_titrant (mL) × Normality × 8000) / Sample_volume (mL)\]\[COD measures total chemically oxidisable organics.\]
- \[Percent removal efficiency = ((C_in - C_out) / C_in) × 100\]\[where C_in and C_out are pollutant concentrations before and after treatment.\]
- \[Dissolved oxygen effect (qualitative relation): higher organic load → higher BOD → lower DO → stress or death for aerobic aquatic life.\]
Effects of Water Pollution
Effects of Water Pollution
Key Point: BOD5 (simple lab estimate) = (DO_initial - DO_after_5_days) × dilution_factor. This gives mg/L of oxygen demanded in 5 days.
Water pollution occurs when harmful substances—chemicals, biological agents, or physical materials—contaminate water bodies. The effects are wide-ranging and affect human health, aquatic life, ecosystems and the economy.
1. Effects on human health
- Contaminated drinking water causes waterborne diseases such as cholera, dysentery, typhoid and hepatitis.
- Chemical contamination (arsenic, fluoride, pesticides, heavy metals like mercury and lead) causes chronic disorders: arsenicosis, fluorosis, neurological damage and cancers.
2. Effects on aquatic life and ecosystems
- Oxygen depletion: Organic wastes increase Biological Oxygen Demand (BOD). Microbial decomposition consumes dissolved oxygen (DO), causing hypoxia and fish kills.
- Eutrophication: Excess nutrients (nitrates, phosphates) trigger algal blooms. When algae die and decompose, DO falls sharply—killing fish and changing the lake/river ecology.
- Bioaccumulation and biomagnification: Persistent toxic substances (e.g., mercury, DDT) accumulate in organisms and concentrate up the food chain, harming predators including humans who eat contaminated fish.
- Habitat loss and biodiversity decline: Pollutants change water chemistry (pH, salinity, turbidity), destroying habitats for sensitive species.
3. Physical and chemical changes
- Increased turbidity reduces light penetration, affecting photosynthesis of aquatic plants.
- pH changes and presence of acids/alkalies can make water unsuitable for many organisms.
- Increased corrosivity and sedimentation affect infrastructure and reservoirs.
4. Economic and social effects
- Decline in fisheries and aquaculture yields; loss of livelihoods for fishing communities.
- Higher costs for water treatment and health care; loss of tourism and recreational value.
- Long-term soil and crop effects where polluted water is used for irrigation.
How these effects develop — an example: eutrophication
- Step 1: Excess nutrients from sewage and fertilizers enter a lake.
- Step 2: Algae grow rapidly (algal bloom), blocking light.
- Step 3: Algae die and decompose; decomposition consumes DO.
- Step 4: Low DO causes fish and other aerobic organisms to die; biodiversity and water quality collapse.
Important indicators to watch: Dissolved Oxygen (DO) — low values indicate poor water quality; Biological Oxygen Demand (BOD) — high values indicate large amounts of degradable organic matter; pH, turbidity, nutrient concentrations (nitrate, phosphate), presence of toxic metals or pathogens.
Prevention and mitigation (brief): Proper sewage treatment, reducing chemical discharge, safe disposal of industrial wastes, controlling agricultural runoff, clean-up of oil spills, banning persistent toxic pesticides and public awareness are key to reducing effects.
- Minamata disease (Japan): Mercury released from a factory bioaccumulated in fish; people who ate the fish suffered severe neurological damage.
- Arsenic contamination in groundwater of parts of West Bengal and Bangladesh causing arsenicosis (skin lesions, internal harm) in affected communities.
- Toledo water crisis (Lake Erie algal blooms, 2014): Toxic cyanobacterial bloom caused drinking-water shutdown for ~400,000 people.
- Oil spills (e.g., Deepwater Horizon): Massive damage to marine life, fisheries and coastal economies.
- Plastic pollution in oceans: Turtles and seabirds ingest plastics or get entangled, leading to injury or death.
- Tannery effluents and industrial discharge polluting rivers (local examples such as sections of the Ganga and Yamuna), reducing fish populations and degrading water quality.
- \[BOD5 (simple lab estimate) = (DO_initial - DO_after_5_days) × dilution_factor\]\[This gives mg/L of oxygen demanded in 5 days.\]
- \[pH = -log10[H+]. pH change affects solubility and toxicity of many pollutants.\]
- \[Conversion: 1 mg/L ≈ 1 ppm for dilute aqueous solutions (useful for pollutant concentration units).\]
- \[Percent DO saturation = (DO_measured / DO_saturation_at_temperature) × 100. (DO_saturation is temperature-dependent: colder water holds more oxygen.)\]
Water Purification Methods (Household and Municipal)
Water Purification Methods (Household and Municipal)
Key Point: Dilution formula (for making disinfectant solutions): C1 × V1 = C2 × V2. Example: To dilute 5% bleach (C1) to 0.1% (C2), calculate V1 for a desired V2.
Overview
Water purification removes physical, chemical and biological contaminants so water becomes safe for drinking and other uses. Purification methods vary by scale: simple, low-cost techniques for households and multi-step processes in municipal treatment plants. The goal is to remove suspended solids, microbes, harmful chemicals and unpleasant taste/odour.
Household methods (common and easy to use)
- Sedimentation: Let dirty water stand undisturbed in a container for several hours. Heavy particles settle to the bottom and clearer water can be decanted.
- Filtration (simple): Passing water through layers of cloth, sand and gravel removes larger particles. A common household filter is a cloth or earthen pot filter.
- Boiling: Bringing water to rolling boil for 1–3 minutes kills most disease-causing microbes (bacteria, viruses, protozoa).
- Solar disinfection (SODIS): Transparent PET bottles filled with water left in sunlight for 6–48 hours. UV-A and heat reduce microbial load. Works best for clear water.
- Chlorination (household dosing): Adding small amounts of household bleach (sodium hypochlorite) or chlorine tablets to achieve a free-chlorine concentration that kills pathogens. Requires correct dilution and contact time.
- Activated carbon: Removes some chemicals, bad taste and odour by adsorption. Often used in combination with other methods.
- Small purifier units: Common home units use a combination of sediment pre-filter, activated carbon, ultraviolet (UV) lamp, ultrafiltration (UF) or reverse osmosis (RO). RO removes dissolved salts and many chemicals; UV kills microbes but does not remove salts.
How to combine household methods (practical approach)
For turbid water: use sedimentation & cloth filtration first → then boil or chlorinate. For clear but microbe-contaminated water: SODIS, boiling or chlorination/UV can be used. For water with high dissolved salts, use RO (if available) or get municipal supply.
Municipal water treatment (typical treatment plant steps)
- Screening: Large objects (leaves, debris) are removed with coarse screens.
- Coagulation and flocculation: Chemicals (coagulants such as alum) are added to destabilize and bind fine suspended particles into larger clumps (flocs) by gentle mixing.
- Sedimentation (clarification): Flocs settle under gravity in large tanks; clear water flows out from the top.
- Filtration: Water passes through rapid sand filters (and sometimes activated carbon) to remove remaining suspended particles and some dissolved compounds.
- Disinfection: Chlorination is commonly used to kill remaining bacteria and maintain a residual disinfectant in the distribution network. Alternatives include ozone and UV treatment.
- pH adjustment & softening (if needed): Chemicals are added to remove hardness (Ca2+, Mg2+) or to adjust pH to prevent corrosion in pipes.
- Storage and distribution: Treated water is stored in tanks/reservoirs and sent through pipes to homes.
Key points about effectiveness
- Physical methods (sedimentation, filtration) remove suspended particles and some microbes attached to particles.
- Thermal and UV methods inactivate microbes but do not remove dissolved chemicals or salts.
- Chemical disinfectants like chlorine are effective against many pathogens and provide residual protection in pipelines, but can react with organics to form by-products if organics are present.
- RO is the most effective at removing dissolved salts and many contaminants, but it wastes water and removes beneficial minerals.
Safety & maintenance tips (household)
- Boil water for at least 1–3 minutes (longer at high altitude) and store in clean covered containers.
- Replace purifier filters and UV lamps as recommended by manufacturer.
- Use correct chlorine dosage—too little is ineffective, too much can be harmful and taste unpleasant.
- Keep storage containers clean and covered to avoid recontamination.
Conclusion
Choosing the right method depends on the type of contamination, available resources and scale. In many situations, combining methods (settling + filtration + disinfection) gives safe drinking water at low cost.
- Household: A family with muddy pond water first lets the water stand for 24 hours (sedimentation), pours it through a cloth and sand filter, then boils the filtered water for drinking.
- Household: Using SODIS — filling clear PET bottles with clear water and leaving them in direct sunlight for a day to disinfect small volumes of drinking water in rural areas.
- Household: Preparing 0.1% chlorine solution from a 5% household bleach using C1V1 = C2V2 to disinfect stored water.
- Municipal: A city treatment plant takes river water: screening → alum is added and flocculated → sedimentation tanks remove flocs → rapid sand filtration → chlorination before distribution.
- Municipal: Coastal city uses a desalination plant (reverse osmosis) to treat seawater into potable water when freshwater sources are scarce.
- \[Dilution formula (for making disinfectant solutions): C1 × V1 = C2 × V2\]\[Example: To dilute 5% bleach (C1) to 0.1% (C2)\]\[calculate V1 for a desired V2.\]
- \[Parts per million (concentration): 1 ppm = 1 mg of substance per litre of water (1 mg/L)\]\[Useful for expressing chlorine residuals and contaminants.\]
- \[Percent removal (%): % removal = ((C_in - C_out) / C_in) × 100\]\[where C_in and C_out are upstream and downstream concentrations.\]
- \[Chlorine dosing concept (simple): Dose_needed ≈ target_residual + chlorine_demand. (Chlorine demand depends on organics/impurities\]\[detailed dosing requires water testing.)\]
Sewage Treatment and Wastewater Management
Sewage Treatment and Wastewater Management
Key Point: BOD5 (simple) = D0 - D5 (D0 = initial dissolved oxygen, D5 = DO after 5 days; for diluted samples multiply by dilution factor)
What is sewage and why treat it?
Sewage (wastewater) is water used in homes, industries and public places that contains human waste, food scraps, detergents and chemicals. If discharged untreated it pollutes rivers, kills aquatic life and spreads disease. Sewage treatment cleans this water so it can be safely returned to the environment or reused.
Main goals of sewage treatment
- Remove suspended solids and settleable matter
- Reduce organic pollution (measured as BOD and COD)
- Reduce pathogens (disease-causing microbes)
- Remove nutrients (nitrogen and phosphorus) if needed
- Manage and dispose of sludge produced
Typical stages of a municipal Sewage Treatment Plant (STP)
1. Preliminary treatment
- Screening: large objects (plastics, rags) are removed by coarse and fine screens.
- Grit chamber: sand, small stones and grit settle out to protect pumps and equipment.
2. Primary treatment
- Primary sedimentation tanks: slower flow allows suspended solids to settle as primary sludge. This removes a significant portion of settleable solids and some organic load.
3. Secondary (biological) treatment
- Biological processes use microbes to break down dissolved and fine suspended organic matter (BOD).
- Common methods: activated sludge process (aeration tanks + settling), trickling filters (biofilm on media), oxidation ponds (large shallow ponds where algae and bacteria interact).
- After biological treatment, the mixture goes to secondary clarifiers where biological solids (activated sludge) settle and are partly returned to the aeration tank.
4. Tertiary (advanced) treatment
- Removes nutrients (nitrates and phosphates), finer suspended matter, and pathogens.
- Processes include filtration, chemical coagulation, biological nutrient removal (nitrification/denitrification) and disinfection (chlorination, UV).
5. Disinfection and disposal/reuse
- Disinfection (chlorine, ozone or UV) reduces disease-causing organisms so the effluent is safe for release or reuse (e.g., irrigation, industrial cooling).
- Treated water is discharged to rivers, lakes or reused depending on quality.
6. Sludge treatment and disposal
- Sludge (from primary and secondary clarifiers) is thickened, stabilized (often by anaerobic digestion) and dewatered.
- Stabilized sludge (biosolids) may be composted, used as fertilizer (after treatment), incinerated or landfilled depending on regulations.
Small-scale and on-site systems
- Septic tanks: Common in rural areas. Solids settle and partial treatment occurs; effluent drains to a soakaway/soil absorption field.
- Constructed wetlands: Natural plants and microbes treat wastewater; low-cost, useful for small communities.
Why it matters (environmental and health points)
- Untreated sewage depletes oxygen in water (kills fish), increases disease risk (cholera, dysentery), and contaminates drinking water sources.
- Treated wastewater when reused conserves fresh water and supports agriculture and industry.
Simple operational tips (wastewater management)
- Reduce water use and avoid pouring harmful chemicals down drains.
- Segregate industrial waste and pre-treat toxic effluents before mixing with municipal sewage.
- Promote decentralized treatment (septic, constructed wetlands) where central STPs are not available.
HTML visual suggestions (for teachers/students)
- Process flow diagram of an STP: show boxes for Screening → Grit chamber → Primary sedimentation → Aeration/biological treatment → Secondary sedimentation → Disinfection → Discharge/Reuse.
- Schematic cross-section of a septic tank and soak pit.
- Layered illustration of activated sludge process showing aeration tank, microbes, flocs and return activated sludge.
- Before-and-after photos/graphics of polluted river vs. river after receiving treated effluent.
Level-appropriate facts
- Domestic sewage typically has BOD in the range of about 100–300 mg/L (values vary).
- Chlorine doses for disinfection are commonly in the order of 0.5–5 mg/L depending on water quality and contact time (set by local standards).
Conclusion
Sewage treatment and wastewater management protect health and the environment by removing solids, reducing organic pollution, killing pathogens and treating nutrients. Understanding the stages and simple formulas helps students appreciate how daily actions (saving water, proper disposal of wastes) affect treatment requirements and environmental quality.
- Municipal Sewage Treatment Plant: A city collects household wastewater and sends it to an STP that uses screening, primary sedimentation, activated sludge, and chlorination before releasing water to a river.
- Septic Tank in a rural home: Solids settle in the tank and partially treated liquid drains into a soak pit where soil microbes further clean it.
- Constructed Wetland for a small village: Wastewater flows slowly through planted beds where plants and bacteria remove pollutants and pathogens.
- Reuse of treated wastewater for irrigation: Treated effluent from an STP used to water public parks or fields, conserving freshwater.
- \[BOD5 (simple) = D0 - D5 (D0 = initial dissolved oxygen\]\[D5 = DO after 5 days\]\[for diluted samples multiply by dilution factor)\]
- \[Percent removal (%) = (C_in - C_out) / C_in × 100 (where C_in = concentration before treatment\]\[C_out = after treatment)\]
- \[Hydraulic Retention Time (HRT) = Volume of tank (m^3) / Flow rate (m^3/day)\]
- \[Mass loading (pollutant) = Flow (Q) × Concentration (C) (e.g.\]\[kg/day = m^3/day × mg/L × 10^-3)\]
- \[Sludge Volume Index (SVI) ≈ Settled sludge volume (mL/L) ÷ MLSS (g/L) (gives mL/g\]\[indicator of settleability)\]
Prevention and Control of Water Pollution
Prevention and Control of Water Pollution
Key Point: Concentration (mg/L) = mass of pollutant (mg) / volume of water (L)
What is water pollution? Water pollution occurs when harmful substances (chemicals, microbes, sewage, plastics, oil, etc.) enter water bodies and make the water unsafe for humans, animals and plants.
Why we must prevent it: Polluted water can cause diseases, kill aquatic life, reduce the usability of water for drinking, farming and industry, and disturb ecosystems.
Main strategies to prevent and control water pollution
- Source reduction (prevent pollution at the source): Use fewer chemicals, proper storage and handling of fuels and industrial chemicals, switch to eco-friendly products, reduce use of single-use plastics and pesticides.
- Sewage treatment: Treat domestic sewage in sewage treatment plants (STPs) before releasing it into rivers or lakes. STPs use physical, biological and chemical methods to remove solids, organic matter and pathogens.
- Industrial effluent treatment: Industries must treat waste water in Effluent Treatment Plants (ETPs) to remove toxic chemicals and heavy metals before discharge or reuse.
- Agricultural measures: Avoid overuse of chemical fertilizers and pesticides; use contour farming, buffer strips and proper timing of application to reduce runoff into water bodies.
- Solid waste management: Proper collection, segregation, recycling and scientific disposal of garbage prevents litter and plastics from reaching water bodies.
- Oil spill control: Quick containment and cleanup using booms, skimmers and absorbents; prevent spills through safer handling and double-hulled tankers.
- Restoration and protection of water bodies: Planting vegetation along banks (riparian belts), dredging to remove accumulated sludge, preventing direct discharge of drains into rivers and creating wetlands to filter water naturally.
- Disinfection and tertiary treatment: After primary (physical) and secondary (biological) treatment, tertiary treatment (filtration, nutrient removal and disinfection with chlorine or UV) ensures safe water for sensitive uses.
- Legislation and monitoring: Laws, standards and regular monitoring help control sources and enforce limits on pollutants (for example permissible limits for BOD, chemical oxygen demand, heavy metals).
- Public awareness and community action: Educating people, community clean-up drives, and local monitoring help reduce littering and illegal dumping.
How treatment works (simple stages)
- Primary treatment: Screening and sedimentation remove large solids and settleable matter.
- Secondary treatment: Biological processes (like activated sludge or trickling filters) remove dissolved organic matter and reduce BOD by using microorganisms.
- Tertiary treatment: Additional filtration, nutrient removal (nitrogen, phosphorus) and disinfection to make water suitable for discharge or reuse.
Important concepts to know (Class 8 level)
- BOD (Biochemical Oxygen Demand): A measure of the amount of dissolved oxygen needed by microorganisms to break down organic matter. Higher BOD means more pollution.
- Eutrophication: Excess nutrients (mainly nitrates and phosphates) cause overgrowth of algae. When algae die and decompose, they consume oxygen and lead to fish kills.
Role of individuals: Do not throw household waste into drains or rivers, use less detergent, dispose of oils and medicines properly, support and use treated wastewater where available, and participate in local cleanliness drives.
Summary: Controlling water pollution needs combined action—controlling sources, treating wastewater, protecting water bodies, enforcing rules and changing people’s habits. These steps protect health, biodiversity and water resources for future generations.
- Sewage treatment plant at a city treating domestic wastewater in stages (primary settling, secondary biological treatment, tertiary disinfection) before releasing the treated water into a river.
- Farmers reducing fertilizer runoff by using buffer strips of grass or trees along fields so less nitrate reaches nearby streams, preventing algal blooms.
- An oil-spill cleanup using floating booms and skimmers to contain and collect oil before it spreads over a large area of sea.
- A paper or textile factory installing an effluent treatment plant to remove dyes and chemicals so that discharged water meets safety standards.
- Community river-cleanup drives that remove plastic and solid waste from river banks, reducing pollution and improving water flow.
- \[Concentration (mg/L) = mass of pollutant (mg) / volume of water (L)\]
- \[Percent removal (%) = ((Cin - Cout) / Cin) × 100\]\[where Cin = influent concentration\]\[Cout = effluent concentration\]
- \[Dilution factor = volume of receiving water / volume of effluent (useful to estimate concentration after mixing)\]
- \[BOD5 (approximate) is measured as the mg of O2 consumed per litre in 5 days\]\[higher BOD → more organic pollution\]
Important Concepts, Terms and Measurements
Important Concepts, Terms and Measurements
Key Point: BOD5 (mg/L) = (D0 - D5) / P, where D0 = initial dissolved oxygen (mg/L), D5 = DO after 5 days (mg/L), P = decimal dilution factor of the sample.
Overview: Pollution occurs when harmful substances (pollutants) enter air or water in amounts that make them unsafe for humans, animals, or the environment. Understanding key concepts and how pollution is measured helps us detect problems and plan solutions.
Key concepts and terms
- Pollutant: Any substance (solid, liquid or gas) that makes the environment harmful. Examples: soot, sulphur dioxide (SO2), nitrate, oil, detergents.
- Primary and secondary pollutants: Primary pollutants are emitted directly from sources (e.g., SO2 from factories, CO from vehicles). Secondary pollutants form in the atmosphere from reactions between primary pollutants (e.g., ground-level ozone formed from NOx and VOCs).
- Particulate matter (PM): Tiny solid or liquid particles suspended in air. PM10 (diameter ≤10 µm) and PM2.5 (≤2.5 µm) are important because they can enter lungs and bloodstream.
- Smog and acid rain: Smog is a haze formed from pollutants (often in cities). Acid rain forms when SO2 and NOx react with water to produce acidic compounds that fall as rain.
- Biochemical Oxygen Demand (BOD): Amount of dissolved oxygen used by microorganisms to decompose organic matter in water over a given period (commonly 5 days at 20 °C, written BOD5). Higher BOD means more organic pollution.
- Chemical Oxygen Demand (COD): Amount of oxygen required to chemically oxidise organic and some inorganic matter in water. COD is usually higher than BOD and reacts faster.
- Dissolved Oxygen (DO): Oxygen dissolved in water. Healthy water bodies have higher DO (needed by fish and aquatic life).
- Turbidity (NTU): Cloudiness of water measured in Nephelometric Turbidity Units. High turbidity often indicates suspended solids and pollutants.
- pH and conductivity: pH indicates acidity/alkalinity; conductivity measures dissolved salts (ions) in water — both important for water quality.
- Air Quality Index (AQI): A single number that communicates how polluted the air is, combining values of several pollutants into categories (Good, Satisfactory, Moderate, Poor, Very Poor, Severe).
How measurements are reported (units and interpretation)
- Air pollutant concentrations: usually in micrograms per cubic meter (µg/m³) for particulate matter, and parts per million (ppm) or micrograms per cubic meter for gases.
- Water pollutant concentrations: commonly in milligrams per litre (mg/L). For dilute aqueous solutions, 1 mg/L ≈ 1 ppm.
- BOD and COD: mg/L. Typical ranges: clean natural water DO ~6–9 mg/L; unpolluted water BOD <3 mg/L; polluted or sewage water BOD can be >100 mg/L. COD for raw sewage commonly 250–800 mg/L (varies widely).
- Turbidity for drinking water should be low (for example <5 NTU is often desirable), while safe pH typically lies near neutral (about 6.5–8.5 depending on guideline).
Instruments and standard methods
- Air monitoring: gravimetric samplers, optical particle counters (for PM2.5/PM10), gas analyzers (for SO2, NOx, CO, O3), and automated AQI monitors.
- Water monitoring: pH meter, DO meter (or Winkler titration method), turbidity meter (nephelometer), BOD incubator method (BOD5), COD chemical titration (dichromate), conductivity meter.
Why these measurements matter: Measurements let us compare against safety standards, spot trends (for example seasonal rises in PM2.5), identify pollution sources (e.g., high nitrate from agricultural runoff), and evaluate treatment efficiency (reduction in BOD/COD after sewage treatment).
- City smog: During winter in many cities, high PM2.5 from vehicle emissions, biomass burning and fog leads to reduced visibility and respiratory problems.
- Eutrophication: Excess fertiliser runoff (nitrates and phosphates) into a lake causes algal blooms, which raise BOD and reduce DO — fish die-offs result.
- Industrial discharge: Untreated factory effluent with high COD and low DO pollutes a river downstream, harming aquatic life and making water unsafe for use.
- Oil spill: Oil on sea surface reduces oxygen exchange and coats birds’ feathers; turbidity and toxicity increase locally.
- Indoor pollution: Burning coal or biomass indoors without ventilation releases CO and particulates, causing health hazards.
- \[BOD5 (mg/L) = (D0 - D5) / P\]\[where D0 = initial dissolved oxygen (mg/L)\]\[D5 = DO after 5 days (mg/L)\]\[P = decimal dilution factor of the sample.\]
- \[COD (mg/L) ≈ (Vb - Vs) × N × 8000 / Vsample\]\[where Vb = volume (mL) of titrant for blank\]\[Vs = volume for sample\]\[N = normality of titrant\]\[Vsample = sample volume in mL. (Used with dichromate method\]\[factor 8000 converts equivalents to mg/L.)\]
- \[AQI sub-index (linear interpolation): I = (Ihi - Ilo)/(BPhi - BPlow) × (C - BPlow) + Ilo\]\[where C = pollutant concentration\]\[BPhi and BPlow are the breakpoints that bracket C\]\[and Ilo and Ihi are the AQI values corresponding to those breakpoints.\]
- \[Conversion (approx.): 1 mg/L ≈ 1 ppm for dilute aqueous solutions.\]
- \[Mass concentration (air): reported in µg/m³ for particulates (no formula needed — instrument measures mass per air volume).\]
Practical Activities, Case Studies and Local Actions
Practical Activities, Case Studies and Local Actions
Key Point: pH = -log10[H+] (pH is a measure of acidity/alkalinity; [H+] is hydrogen ion concentration in moles per litre)
Overview
This topic focuses on hands-on activities, real-life case studies and community-level actions that help students understand sources, effects and control of air and water pollution. Practical work makes abstract concepts concrete—measuring indicators (pH, turbidity, dissolved oxygen), observing particulate deposition, building simple filters, and carrying out local surveys and awareness drives. Case studies show how policies, technology and community action reduce pollution.
Practical activities (what and why)
- Air pollution tests: Collect soot on white paper near a roadside to compare particulate deposition at different distances/time of day; compare vehicle-heavy streets with quieter streets to observe particulate levels.
- Water quality tests: Measure pH using litmus or red-cabbage indicator, test turbidity with a turbidity tube or secchi disk substitute, estimate dissolved oxygen (DO) with a simple DO kit or compare water samples visually for signs of life.
- BOD demonstration: Set up sealed bottles of polluted and clean water; measure DO initially and after 5 days of incubation (in dark). BOD gives the oxygen demand and indicates organic pollution.
- Filtration model: Make a layered sand–gravel–charcoal filter to show mechanical and adsorption removal of suspended solids and some pollutants.
- Indicator experiments: Use red-cabbage extract to test pH of various local water samples and detergents to illustrate acidity/alkalinity impacts.
How to plan a student project
- Define a clear question: e.g., "How does distance from a busy road affect soot deposition?" or "How does household wastewater affect DO of a local pond?"
- Choose indicators (pH, turbidity, DO, visible oil/foam, presence of aquatic life), select sampling locations and times, record data systematically, and use simple statistics/graphs to present results.
- Include safety: use gloves, avoid tasting samples, handle chemicals carefully, and get teacher/supervisor approval for field visits.
Case studies (what to learn)
Study real examples such as major city air-pollution episodes, river-cleanup initiatives (for example large river-cleaning programs), and local school/municipal actions. From case studies, extract causes, stakeholders, technical solutions used, and social measures (laws, behaviour change).
Local actions students can take
- Organise clean-ups and segregated waste collection drives.
- Plant trees and create green buffers near roads and water bodies.
- Promote rainwater harvesting, home composting and reduce single-use plastics.
- Engage the community and local council with simple monitoring reports (pH/turbidity/soot observations) and awareness posters.
Learning outcomes
Students should be able to measure basic pollution indicators, interpret results, relate local observations to larger pollution sources, suggest practical remedial actions and communicate findings to the community.
Safety and ethics
Always use protective gear, do not disturb wildlife, obtain permission for sampling on private land, and report hazardous findings to appropriate authorities rather than attempting risky remediation.
- Soot deposition test: Fix 3 white cards at 5 m, 15 m and 50 m from a busy road for one week. Compare blackening to show how particulate pollution decreases with distance.
- Red-cabbage pH test: Make an indicator from boiled red cabbage. Test tap water, pond water and factory discharge (if accessible). Note colour changes—acidic samples turn reddish, alkaline turn greenish/blue.
- Simple water filter: Construct a bottle filter with cotton, sand, gravel and activated charcoal layers. Pour muddy water and observe reduced turbidity, demonstrating mechanical removal and adsorption.
- BOD demonstration: Fill two airtight bottles with equal volumes of pond water and treated tap water. Measure dissolved oxygen (DO) on Day 0 and Day 5. The greater the decrease, the higher the BOD and organic pollution.
- Local awareness drive: Students collect data on plastic waste around a market, prepare a short report and meet the local councillor asking for more dustbins and a ban on single-use plastic in that area.
- \[pH = -log10[H+] (pH is a measure of acidity/alkalinity\]\[[H+] is hydrogen ion concentration in moles per litre)\]
- \[BOD (approx) = DO_initial - DO_after_5days (units: mg/L\]\[used in simple BOD5 tests)\]
- \[Concentration in ppm (water\]\[approximate) = mg of solute per litre of water (1 ppm ≈ 1 mg/L for dilute aqueous solutions)\]
- \[Percent reduction = ((Initial value - Final value) / Initial value) × 100% (useful to show improvement after an intervention\]\[e.g.\]\[turbidity or pollutant concentration)\]
Key Concepts
- Air pollution
- Presence of harmful substances in the atmosphere that can cause health problems or environmental damage.
- Water pollution
- Contamination of water bodies by harmful chemicals, microbes or waste, reducing water quality and harming life.
- Pollutant
- Any physical, chemical or biological substance that causes pollution.
- Primary pollutant
- A pollutant emitted directly from a source into the environment.
- Secondary pollutant
- A pollutant formed in the environment by chemical reactions between primary pollutants.
- Particulate matter (PM2.5/PM10)
- Tiny solid or liquid particles suspended in air that can be inhaled and harm health.
- Carbon monoxide (CO)
- A colorless, odorless toxic gas produced by incomplete combustion of carbon-containing fuels.
- Sulphur dioxide (SO2)
- A gas produced by burning sulphur-containing fuels that irritates respiratory systems and forms acid rain.
- Nitrogen oxides (NOx)
- Gases produced by high-temperature combustion that contribute to smog and acid rain.
- Smog
- A mixture of smoke and fog or pollutants that reduces visibility and harms health.
- Photochemical smog
- Smog formed by sunlight-driven reactions of NOx and VOCs, producing ozone and other oxidants.
- Acid rain
- Rain or precipitation made acidic by dissolved sulphur dioxide and nitrogen oxides, damaging ecosystems and structures.
- Greenhouse gases
- Gases like CO2 and CH4 that trap heat in the Earth's atmosphere and cause the greenhouse effect.
- Global warming
- Long-term rise in Earth's average surface temperature due to increased greenhouse gas concentrations.
- Eutrophication
- Enrichment of water bodies with nutrients (usually nitrates and phosphates) causing algal blooms and oxygen depletion.
- Sewage
- Wastewater from households that contains organic matter, pathogens and nutrients.
- Biological Oxygen Demand (BOD)
- A measure of the amount of dissolved oxygen needed by microorganisms to decompose organic matter in water.
- Thermal pollution
- Increase in water temperature caused by discharge of heated industrial or power-plant effluents, affecting aquatic life.
- Industrial effluent
- Liquid waste discharged from factories that may contain toxic chemicals, heavy metals or dyes.
- Biodegradable pollutant
- A pollutant that can be broken down naturally by microorganisms into harmless substances.
Practice Questions
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Which gas is produced by incomplete combustion in vehicle engines and is dangerous to humans? / वाहन के इंजनों में अधूरे दहन से कौन-सी गैस उत्पन्न होती है जो मनुष्यों के लिए खतरनाक है? (a) Oxygen / ऑक्सीजन (b) Carbon monoxide / कार्बन मोनोऑक्साइड (c) Nitrogen / नाइट्रोजन (d) Carbon dioxide / कार्बन डाइऑक्साइड
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(b) Carbon monoxide / कार्बन मोनोऑक्साइड — Incomplete combustion of carbon-based fuels produces CO (2C + O₂ → 2CO). CO is colourless, odourless, and dangerous because it reduces the blood's ability to carry oxygen. / कार्बन युक्त ईंधन के अधूरे दहन से CO बनती है। CO रंगहीन, गंधहीन और खतरनाक गैस है क्योंकि यह रक्त की ऑक्सीजन ले जाने की क्षमता कम करती है।
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Acid rain is primarily caused by which two pollutants reacting with water in the atmosphere? / वर्षाम्ल मुख्यतः वायुमंडल में पानी के साथ अभिक्रिया करने वाले किन दो प्रदूषकों से बनती है? (a) CO₂ and methane / CO₂ और मीथेन (b) SO₂ and NOₓ / SO₂ और NOₓ (c) Ozone and dust / ओज़ोन और धूल (d) CFCs and water vapor / CFC और जलवाष्प
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(b) SO₂ and NOₓ / SO₂ और NOₓ — Sulfur dioxide and nitrogen oxides react with water and oxygen in the atmosphere to form sulfuric acid and nitric acid, which fall as acid rain. / सल्फर डाइऑक्साइड और नाइट्रोजन ऑक्साइड वायुमंडल में जल और ऑक्सीजन से अभिक्रिया करके सल्फ्यूरिक अम्ल और नाइट्रिक अम्ल बनाते हैं जो अम्लीय वर्षा के रूप में गिरते हैं।
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What is eutrophication? In which type of pollution does it occur? / सुपोषण (यूट्रोफिकेशन) क्या है? यह किस प्रकार के प्रदूषण में होता है? (a) Air pollution caused by smoke / धुएँ से वायु प्रदूषण (b) Water pollution caused by excess nutrients leading to algal blooms and oxygen depletion / अतिरिक्त पोषक तत्वों से जल प्रदूषण जिससे शैवाल की अत्यधिक वृद्धि और ऑक्सीजन की कमी होती है (c) Soil pollution caused by pesticides / कीटनाशकों से मृदा प्रदूषण (d) Noise pollution in rivers / नदियों में ध्वनि प्रदूषण
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(b) Water pollution caused by excess nutrients leading to algal blooms and oxygen depletion / अतिरिक्त पोषक तत्वों से जल प्रदूषण जिससे शैवाल की अत्यधिक वृद्धि और ऑक्सीजन की कमी होती है — Eutrophication occurs in water bodies when excess nitrates and phosphates (from agricultural runoff or sewage) cause rapid algal growth; when algae die and decompose, dissolved oxygen is depleted, killing fish. / नदियों/झीलों में अतिरिक्त नाइट्रेट और फॉस्फेट (कृषि अपवाह या सीवेज) से शैवाल तेज़ी से बढ़ते हैं; मरने पर उनके अपघटन से ऑक्सीजन खत्म होती है, मछलियाँ मर जाती हैं।
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A major source of water pollution in Indian rivers is _______ sewage discharged without treatment. / भारतीय नदियों में जल प्रदूषण का एक प्रमुख स्रोत बिना उपचार के छोड़ा गया _______ सीवेज है।
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Domestic/untreated / घरेलू/अनुपचारित — Untreated domestic sewage contains organic matter, pathogens and nutrients that raise BOD, spread waterborne diseases and cause eutrophication. / अनुपचारित घरेलू सीवेज में कार्बनिक पदार्थ, रोगजनक और पोषक तत्व होते हैं जो BOD बढ़ाते हैं, जलजनित बीमारियाँ फैलाते हैं और सुपोषण का कारण बनते हैं।
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Particulate matter with diameter ≤ 2.5 µm is called _______ and is more harmful because it penetrates deep into the lungs. / 2.5 µm या उससे कम व्यास वाले कणीय पदार्थ को _______ कहते हैं और यह अधिक हानिकारक है क्योंकि यह फेफड़ों में गहराई तक प्रवेश करता है।
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PM2.5 / PM2.5 — PM2.5 particles are so small they bypass the nose and throat and reach deep into the lungs and even bloodstream, causing serious respiratory and cardiovascular diseases. / PM2.5 कण इतने छोटे होते हैं कि नाक और गले को पार करके फेफड़ों में गहराई तक तथा रक्त में भी पहुँच जाते हैं, जिससे गंभीर श्वसन और हृदय रोग होते हैं।
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True or False: An electrostatic precipitator is used to remove gaseous pollutants like SO₂ from factory chimneys. / सत्य या असत्य: फ़ैक्ट्री की चिमनियों से SO₂ जैसे गैसीय प्रदूषकों को हटाने के लिए स्थिर-वैद्युत अवक्षेपक (इलेक्ट्रोस्टैटिक प्रेसिपिटेटर) का उपयोग किया जाता है।
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False / असत्य — Electrostatic precipitators are used to remove particulate matter (fly ash, dust) from flue gases, not gaseous pollutants like SO₂. Wet scrubbers or other chemical methods are used to remove SO₂. / स्थिर-वैद्युत अवक्षेपक का उपयोग फ्लू गैसों से कणीय पदार्थ (राख, धूल) हटाने के लिए होता है, SO₂ जैसी गैसों के लिए नहीं। SO₂ हटाने के लिए गीले स्क्रबर या रासायनिक विधियाँ प्रयुक्त होती हैं।
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What is the difference between a primary pollutant and a secondary pollutant? Give one example of each. / प्राथमिक प्रदूषक और द्वितीयक प्रदूषक में क्या अंतर है? प्रत्येक का एक उदाहरण दीजिए।
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A primary pollutant is emitted directly from a source (e.g., carbon monoxide from vehicle exhaust). A secondary pollutant is formed in the atmosphere by chemical reactions between primary pollutants and other substances (e.g., ground-level ozone formed when NOₓ and VOCs react in sunlight). / प्राथमिक प्रदूषक सीधे स्रोत से उत्सर्जित होता है (जैसे वाहन से कार्बन मोनोऑक्साइड)। द्वितीयक प्रदूषक वायुमंडल में प्राथमिक प्रदूषकों और अन्य पदार्थों की रासायनिक अभिक्रियाओं से बनता है (जैसे NOₓ और VOC सूर्यप्रकाश में मिलकर ज़मीनी ओज़ोन बनाते हैं)।
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List any two methods a family can follow at home to help reduce air pollution and two methods to prevent water pollution. / एक परिवार घर पर वायु प्रदूषण कम करने के लिए कोई दो और जल प्रदूषण रोकने के लिए कोई दो उपाय बताइए।
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To reduce air pollution: (1) Use LPG or clean cooking fuel instead of wood/coal. (2) Avoid burning garbage or leaves in the open. To prevent water pollution: (1) Do not throw garbage or chemicals into drains or rivers. (2) Use the correct amount of fertilisers and pesticides in gardens to reduce runoff. / वायु प्रदूषण कम करने के लिए: (1) लकड़ी/कोयले की जगह LPG या स्वच्छ ईंधन उपयोग करें। (2) खुले में कचरा या पत्तियाँ न जलाएँ। जल प्रदूषण रोकने के लिए: (1) नालियों या नदियों में कचरा या रसायन न डालें। (2) बगीचे में सही मात्रा में उर्वरक और कीटनाशक का उपयोग करें ताकि अपवाह कम हो।
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